Boltzmann distribution

Article on other languages:

del.icio.us del.icio.us
Digg Digg
Furl Furl
Reddit Reddit
Rojo Rojo
Add to OnlyWire

In physics and mathematics, the Boltzmann distribution is a certain distribution function or probability measure for the distribution of the states of a system. It underpins the concept of the canonical ensemble, providing its underlying distribution. A special case of the Boltzmann distribution, used for describing the velocities of particles of a gas, is the Maxwell-Boltzmann distribution. In more general mathematical settings, the Boltzmann distribution is also known as the Gibbs measure.

The Boltzmann distribution for the fractional number of particles Ni / N occupying a set of states i which each respectively possess energy Ei:

{{N_i}\over{N}} = {{g_i e^{-E_i/(k_BT)}}\over{Z(T)}}

where kB is the Boltzmann constant, T is temperature (assumed to be a sharply well-defined quantity), gi is the degeneracy, or number of states having energy Ei, N is the total number of particles:

N=\sum_i N_i\,

and Z(T) is called the partition function, which can be seen to be equal to

Z(T)=\sum_i g_i e^{-E_i/(k_BT)}.

Alternatively, for a single system at a well-defined temperature, it gives the probability that the system is in the specified state. The Boltzmann distribution applies only to particles at a high enough temperature and low enough density that quantum effects can be ignored, and the particles are obeying Maxwell–Boltzmann statistics. (See that article for a derivation of the Boltzmann distribution.)

The Boltzmann distribution is often expressed in terms of β = 1/kT where β is referred to as thermodynamic beta. The term e^{-\beta E_i} or e^{-E_i/(kT)}, which gives the (unnormalised) relative probability of a state, is called the Boltzmann factor and appears often in the study of physics and chemistry.

When the energy is simply the kinetic energy of the particle

E_i = {\begin{matrix} \frac{1}{2} \end{matrix}} mv^{2},

then the distribution correctly gives the Maxwell–Boltzmann distribution of gas molecule speeds, previously predicted by Maxwell in 1859. The Boltzmann distribution is, however, much more general. For example, it also predicts the variation of the particle density in a gravitational field with height, if E_i = {\begin{matrix} \frac{1}{2} \end{matrix}} mv^{2} + mgh. In fact the distribution applies whenever quantum considerations can be ignored.

In some cases, a continuum approximation can be used. If there are g(E) dE states with energy E to E + dE, then the Boltzmann distribution predicts a probability distribution for the energy:

p(E)\,dE = {g(E) e^{-\beta E}\over {\int g(E') e^{-\beta E'}}\,dE'}\, dE.

Then g(E) is called the density of states if the energy spectrum is continuous.

Classical particles with this energy distribution are said to obey Maxwell–Boltzmann statistics.

In the classical limit, i.e. at large values of E / (kT) or at small density of states — when wave functions of particles practically do not overlap — both the Bose–Einstein or Fermi–Dirac distribution become the Boltzmann distribution.

Derivation

See Maxwell–Boltzmann statistics.

See also

Probability distributions
 
Discrete univariate with infinite support
Retrieved from "http://en.wikipedia.org/wiki/Boltzmann_distribution"

This article is from Wikipedia. All text is available under the terms of the GNU Free Documentation License.

Giant Panda

Mercedes Car
James Bond Guide
This site monitored by SitePinger.net